Journal
JOURNAL OF LUMINESCENCE
Volume 215, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2019.116648
Keywords
Optical properties; Thermal stability; SrBi2Ta2O9:Sm3+; Orange-red phosphor
Categories
Funding
- Natural Science Foundation of Shaanxi Province [2018JM5055]
- Fundamental Research Funds for the Central Universities [2452019076]
- Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications [2019XGJSKFJJ01]
- Construction Program of the key discipline in Hunan Province
- Projects of the Education Department of Hunan Province [18A465]
- Science and Technology Plan Project of Chenzhou city [jsyf2017014]
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A new orange-red SrBi2Ta2O9:Sm3+ phosphor is prepared via high-temperature solid-state route in air atmosphere. The phase purity of phosphor is characterized using X-ray diffraction (XRD). The phosphor shows the intense excitation peak at 403 nm and emits bright orange-red light at 564, 600, 647, and 701 nm in photoluminescence (PL) spectrum. Among them, the strongest peak is located at 600 nm due to (4)G(5/2)- H-6(7/2) transition of Sm3+. The critical transfer distance of Sm3+ is calculated as 26.31 angstrom. The optimal doping concentration is determined to be about 2 mol%. The temperature dependent emission spectra exhibit excellent thermal stability. The Commission International de L'Eclairage (CIE) coordinates of the SrBi2Ta2O9:xSm(3+) (0.005 <= x <= 0.30) are located in the reddish orange region. These results indicate that the orange-red emitting SrBi2Ta2O9:Sm3+ phosphor can be used as potential substitute red phosphors for white light emitting diodes (w-LEDs).
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