Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 138, Issue -, Pages 107-115Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2019.06.011
Keywords
alpha-Zingiberene; beta-Sesquiphellandrene; (-) ar-curcumene; Vapor pressure, vaporization enthalpy; Correlation-gas chromatography
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The vaporization enthalpies and vapor pressures of three major components in ginger, alpha-zingiberene, beta-sesquiphellandrene, and (-) ar-curcumene are evaluated by correlation gas chromatography using two set of standards, n-alkanes and a series of cyclic and polycyclic hydrocarbons. Vaporization enthalpies are reproduced by both sets of standards. Vapor pressures as a function of temperature are fit to a second order polynomial and the results compared to available literature data. Vapor pressures as evaluated by both sets of standards are in general agreement at ambient temperatures but begin to diverge somewhat at elevated temperatures. The n-alkanes appear to provide the best agreement with the limited amount of available experimental data. (C) 2019 Elsevier Ltd.
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