Journal
JOURNAL OF CATALYSIS
Volume 379, Issue -, Pages 33-38Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2019.09.015
Keywords
Molybdenum sulphide; Titanium dioxide; Heterogeneous photocatalysis; Semi-hydrogenation; Isomerization
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Funding
- Natural Sciences and Engineering Research Council of Canada
- Canada Foundation for Innovation
- Canada Research Chairs Program
- RISE program
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Earth abundant materials, Mo and Co, are used to decorate TiO2 and work as co-catalyst for the selective semi-hydrogenation of alkynes and isomerization of estragole in a H-2-free environment under UVA irradiation. Catalytic efficiency is higher than highly-reactive Pd-decorated TiO2, using lower metal loadings and showing better selectivity towards the semi-hydrogenation reaction. (C) 2019 Elsevier Inc. All rights reserved.
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