Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 817, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.152768
Keywords
All-inorganic perovskite solar cells; Zinc oxide; Carbon electrode
Categories
Funding
- National Natural Science Foundation of China [51302021]
- Postgraduate Research Innovation Project of Changsha University of Technology [CX2019SS41]
- Research-based Learning and Innovative Experiment Program for College Students in Hunan Province in 2018
- Education Department of Hunan Province, China [18A149]
- International Collaboration Program (CSUST) [2018IC28]
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In this paper, all-inorganic, hole-transporting-layer-free (HTLF), carbon-based CsPbIBr2 planar solar cells with zinc oxide (ZnO) as electron-transporting materials (ETMs) were studied for the first time. The reported all-inorganic, HTLF, carbon-based cesium lead iodide dibromide (CsPbIBr2) solar cells used titanium dioxide (TiO2) as ETMs, which usually required a high sintering temperature of 500 degrees C. Here, ZnO ETMs were annealed at 120 degrees C. The highest power conversion efficiency (PCE) of 7.60%, with a short-circuit current (J(sc)) of 11.60 mA/cm(2), an open-circuit voltage (V-oc) of 1.03 V and the fill factor (FF) of 0.63, was obtained. Furthermore, the thermal and humid stabilities of the solar cells were studied. The perovskite solar cells were placed at 10% humidity and room temperature for 624 h and the PCE of perovskite solar cells only decreased by 10%. While the perovskite solar cells were placed at 80 degrees C and 0% humidity for 192 h, the PCE of the solar cells decreased by 4%. (C) 2019 Elsevier B.V. All rights reserved.
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