4.7 Article

Thermochromic, threshold switching, and optical properties of Cr-doped VO2 thin films

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 806, Issue -, Pages 310-315

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.07.264

Keywords

Vanadium dioxide; Sol-gel; Phase transition temperature; Cr-doped; Threshold switching

Funding

  1. National Research Council of Science and Technology Major Project [2017ZX02301007-002]
  2. National Natural Science Foundation of China [51571152]
  3. Yellow Crane Talent Plan of Wuhan

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In this paper, undoped and Cr-doped VO2 thin films were fabricated and deposited onto Al2O3 substrates using a sol-gel method. Then, the effects of Cr-doping on the thermochromic, and optical properties of the thin films were investigated. Doping with Cr ions gradually increased the metal-insulator transition (MIT) temperature of the films, while the luminous transmittance (T-lum) and the sol modulation efficiency (Delta T-sol) gradually decreased. Additionally, Pt/VO2/ITO devices and Cr-doped VO2 devices were prepared to study their threshold switching (TS) properties. For devices fabricated with Cr-doped VO2 films, both the threshold voltage (Vth+) and the OFF-state current decreased as the amount of Cr doping increased. In contrast, the ON/OFF ratio increased from 10(4) to 10(5). These results provide insight into the potential for using VO2 in thermochromic, optical, and TS applications. (C) 2019 Elsevier B.V. All rights reserved.

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