4.7 Article

One-step microwave synthesis of NiO/NiS@CNT nanocomposites for high-cycling-stability supercapacitors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 806, Issue -, Pages 170-179

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.07.213

Keywords

Supercapacitors; Nickel oxide; Nickel sulfide; CNT; Cycling stability

Funding

  1. National Natural Science Foundation of China [40501332]
  2. National Key Research and Development Program of China [2017YFD02018018]
  3. Natural Science Foundation of Shanxi Province [2016JQ3005]
  4. Project of Promoting Agricultural Science and Technology Demonstration of Yangling [2018-GG-29]

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NiO/NiS@CNT and NiO@CNT nanocomposites were rapidly fabricated using a one-step microwave method in 60 s. The electrochemical performances of the prepared electrodes with different mass ratios and microwave conditions for supercapacitors were investigated. NiO/NiS@CNT showed a high specific capacitance of 809.7 F g(-1) at 1 A g(-1) and tremendous cycling stability of approximately 100% retention after 20 000 cycles at 5 A g(-1), indicating better electrochemical performance than NiO@CNT. The asymmetric supercapacitor device based on NiO/NiS@CNT//activated carbon (AC) displayed high energy and power density and excellent cycling stability, demonstrating enormous potential for energy-storage applications. (C) 2019 Elsevier B.V. All rights reserved.

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