Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 805, Issue -, Pages 522-530Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.07.044
Keywords
Lithium ion batteries; High Coulombic efficiency; Synergistic effect; Graphitic carbon nitride; Anode
Categories
Funding
- Australian Research Council [DP150104365, DP160104835]
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The spinel oxide NiCo2O4 is regarded as a desirable electrode material in lithium-ion batteries with high performance due to its better electrochemical activity and higher capacity compared to traditional simple oxides. However, lithium-ion batteries with this conversion reaction anode still suffer from low initial Coulombic efficiency accompanied by the generation of solid electrolyte interface layer. Herein, a facile strategy is proposed to couple nanoparticulate NiCo2O4 with g-C3N4, which effectively reduces solid electrolyte interface formation and leads to a high initial Coulombic efficiency. Various characterization techniques confirm that NiCo2O4 nanoparticles grow homogeneously on g-C3N4 nanosheets. This NiCo2O4/g-C3N4 hybrid, as an anode material for lithium-ion batteries, can reach an initial Coulombic efficiency of 84.5%, which is attributed to low interfacial surface area and high discharge potential of electrodes. Owing to the synergistic effect in the NiCo2O4/g-C3N4 hybrid, excellent reversible capacities of 1252 and 476 mAh g(-1) are maintained at respective current densities of 100 and 500 mA g(-1) after 100 cycles. The highly reversible lithium storage is a result of high NiCo2O4 electrode performance, unique layered structure, and excellent g-C3N4 properties. (C) 2019 Elsevier B.V. All rights reserved.
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