Performance and long-term durability of direct-methane flat-tube solid oxide fuel cells with symmetric double-sided cathodes

In this work, we investigated the performance and stability of a large flat-tube SOFC with symmetric double-sided cathodes (DSC), which was directly fueled with methane. The effect of steam/carbon (S/C) ratio, temperature, and current density on the performance, and long-term stability of the DSC as well as the catalytic behavior of the anode was investigated in details. The thick anode support and inner channels of the DSC formed an efficient micro-reactor for steam-reforming of methane, resulting in high conversion rate of methane and CO selectivity. In particular, when the S/C was 2, the conversion of CH4 at 750 degrees C achieved 100% in the DSC and no carbon deposition was observed. Moreover, the voltage of DSC with was stable throughout 190 h under a discharge current density of 0.257 A cm(-2). (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.