Journal
INORGANIC CHEMISTRY
Volume 58, Issue 24, Pages 16372-16378Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01845
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Funding
- German Research Foundation (Deutsche Forschungsgemeinschaft DFG) [GR 4451/1-1, HU 2512/1-1]
- DFG [GR 4451/2-1, BE 3716/7-1]
- Australian Nuclear Science and Technology Organisation (ANSTO) under the Bragg Institute [4766, 5279]
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A proximity enforcing diarylsilane ligand is reported, which gives rise to unusual Si-H center dot center dot center dot M interactions with the d(10) metal ions Cu+ and Ag+ upon complexation. These interactions are studied in detail both experimentally and computationally and can be classified to be weakly agostic in nature for the Si-H center dot center dot center dot Cu interaction. The Si-H center dot center dot center dot Ag interaction has more signatures of an electrostatic contact.
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