Journal
INORGANIC CHEMISTRY
Volume 58, Issue 22, Pages 15013-15016Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02203
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Funding
- National Natural Science Foundation of China [U1504202, 21971100, 21771097]
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Highly dense packing of chromophoric linkers is achieved in a novel pyrene-based metal-organic framework (MOF), [Zn(TBAPy)(1/2)(H2O)(2)], induced by an ionic liquid. This MOF displays a quick response to visible-light irradiation (photocurrent density of up to 4.492 mu A cm(-2)) and is capable of repetitive on-off photocurrent switching with a large on-off ratio (37.55).
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