Journal
INORGANIC CHEMISTRY
Volume 58, Issue 22, Pages 15417-15422Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02519
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG)
Ask authors/readers for more resources
We present the coordination chemistry of the cyclodimethylsiloxanes D-6 and D-7 toward alkaline earth metal salts. The coordination chemistry of these macrocycles toward alkaline earth metals has been unprecedented to date, and we could show that these ligands coordinate better than previously thought. Direct reaction of alkaline earth metal salts with these ligands yields stable complexes even with a relatively strongly coordinating iodide anion. A handful of counterintuitive coordination compounds could be characterized by single-crystal X-ray diffraction analysis. Quantum chemical calculations of suited Born-Haber cycles showed that these complexes are indeed stable, for Mg(2+ )and Ca2+ even with iodide employed as the anion and for Sr2+ and Ba2+ in the presence of GaI3.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available