Journal
ENERGY & FUELS
Volume 34, Issue 2, Pages 2178-2184Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.9b02811
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Funding
- National Key R&D Program of China [2018YFB1501504]
- National Natural Science Foundation of China [51476175, 51536009]
- Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BTO1N092]
- CAS Pioneer Hundred Talents Plan
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Furfural (FAL), a promising renewable platform compound from biomass, can be totally hydrogenated to an industrially important platform chemical, tetrahydrofurfuryl alcohol (THFA). In this work, a high yield of THFA was obtained by one-pot hydrogenation of FAL over a PtNi catalyst under mild reaction conditions. Small PtNi alloy particles were well distributed on active carbon. The catalysts were characterized by several physical-chemical technologies (transmission electron microscopy, X-ray diffraction, energy-dispersive spectroscopy, and inductively coupled plasma spectroscopy). Temperature-programmed reduction with hydrogen and in situ X-ray photoelectron spectroscopy demonstrate the presence of PtNi alloy. The electron-rich metal Pt could facilitate the heterolytic dissociation of hydrogen and promote the hydrogenation of FAL. Pt sites on the surface facilitate the adsorption at aldehyde (C=O) groups, and the furan ring strongly adsorbs on the Ni surface. Low reaction temperature is advantageous to reduce side reactions. Various metal concentrations were employed in this reaction; Pt(3)Ni(3)/C catalyst exhibits the best performance, achieving 99% FAL conversion and 93% THFA yield at 35 degrees C and under 2 MPa H-2.
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