4.5 Article

From Thermal to Electroactive Graphene Nanofluids

Journal

ENERGIES
Volume 12, Issue 23, Pages -

Publisher

MDPI
DOI: 10.3390/en12234545

Keywords

graphene; reduced graphene oxide (rGO); nanofluids; thermal properties; heat transfer fluids; electrochemical energy storage; electroactive nanofluids

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Funding

  1. Severo Ochoa Program (MINECO) [SEV-2017-0706]
  2. CERCA Programme/Generalitat de Catalunya
  3. Spanish Ministry (MCIU/AEI/FEDER, UE) [MAT2015-68394-R, RTI2018-099826-B-I00]

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Here, we describe selected work on the development and study of nanofluids based on graphene and reduced graphene oxide both in aqueous and organic electrolytes. A thorough study of thermal properties of graphene in amide organic solvents (N,N-dimethylformamide, N,N-dimethylacetamide, and N-methyl-2-pyrrolidone) showed a substantial increase of thermal conductivity and specific heat upon graphene integration in those solvents. In addition to these thermal studies, our group has also pioneered a distinct line of work on electroactive nanofluids for energy storage. In this case, reduced graphene oxide (rGO) nanofluids in aqueous electrolytes were studied and characterized by cyclic voltammetry and charge-discharge cycles (i.e., in new flow cells). In addition, hybrid configurations (both hybrid nanofluid materials and hybrid cells combining faradaic and capacitive activities) were studied and are summarized here.

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