Journal
ELECTROCHIMICA ACTA
Volume 321, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.134716
Keywords
Li-O-2 battery; Oxygen electrode; Electrocatalyst; Free-standing structure
Categories
Funding
- Science and Technology Department of Sichuan Province [2019YJ0503]
- Cultivating Program of Middle Aged Key Teachers of CDUT [KYGG201709]
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Interface engineering is crucial strategy for the sensible design and synthesis of high-efficiency electrocatalysts. However, the study on the effect of interfacial heterogeneity on the kinetics of oxygen electrode reactions in lithium-oxygen (Li-O-2) batteries tends to be neglected, which restricts the development of excellent performance Li-O-2 batteries. Here, a cactus-like nickel-cobalt oxide and nickel oxide heterostructure (NCO@NO) was successfully prepared and used for Li-O-2 batteries as catalyst. The built-in electric field at the heterogeneous interface between NiO and NiCo2O4 can significantly enhance the interface charge transfer kinetics, and its unique cactus-like structure facilitates the exposure of abundant catalytic active sites. Due to the synergistic interaction between surface structure and heterogeneous interface, the NCO@NO based cathode exhibits a large discharge capacity of 17463.5 mA h g(-1), an improved overpotential of 0.98 V, and an excellent long-term cycle stability (the terminal discharge voltage of the NCO@NO based Li-O-2 battery shows negligible attenuation after cycling up to 500 times). (C) 2019 Elsevier Ltd. All rights reserved.
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