Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 37, Issue 12, Pages 1223-1228Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201900346
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21672119, 21975135]
- China Postdoctoral Science Foundation [2018M641624]
Ask authors/readers for more resources
The Summary of main observation and conclusion Converting CO2 into value-added chemicals represents a promising way to alleviate the CO2 derived environmental issues, for which the development of catalysts with high efficiency and recyclability is very desirable. Herein, the catalytic system by combining cobalt source and ionic liquid (IL) has been developed as the efficacious and recyclable catalyst for the carboxylative cyclization of propargylic amine and CO2 to prepare 2-oxazolinones. In this protocol, various propargylic amines were successfully transformed into the corresponding 2-oxazolinones with CoBr2 and diethylimidazolium acetate ([EEIM][OAc]) as the catalyst under atmospheric CO2 pressure. It is worth noting that the turnover number (TON) of this transformation can be up to 1740, presumably being attributed to the cooperative effect of the cobalt and IL. Furthermore, the existence of IL enables the catalytic system to be easily recycled to 10 times without losing its activity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available