Journal
CHEMSUSCHEM
Volume 12, Issue 22, Pages 5051-5058Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201902194
Keywords
batteries; conductive metal-organic frameworks; high-rate anodes; lithium storage; nanowires
Funding
- National Natural Science Foundation of China [51772127, 51772131, 51802119]
- Taishan Scholars [ts201712050]
- Major Program of Shandong Province Natural Science Foundation [ZR2018ZB0317]
- Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong
Ask authors/readers for more resources
Conductive metal-organic frameworks (MOFs), as a newly emerging multifunctional material, hold enormous promise in electrochemical energy-storage systems owing to their merits including good electronic conductivity, large surface area, appropriate pore structure, and environmental friendliness. In this contribution, a scalable solvothermal strategy was devised for the bottom-up fabrication of 1D Cu-based conductive MOF, that is, Cu-3(2,3,6,7,10,11-hexahydroxytriphenylene)(2) (Cu-CAT) nanowires (NWs), which were further utilized as a competitive anode for lithium-ion batteries (LIBs). The intrinsic Li storage mechanism of the Cu-CAT electrode was also explored. Benefiting from its structural virtues, the resultant 1D Cu-CAT NWs were endowed with superb Li+ diffusion coefficients and electrochemical conductivities and exhibited remarkably high-rate reversible capacities of approximately 631 mAh g(-1) at 0.2 A g(-1) and even approximately 381 mAh g(-1) at 2 A g(-1), along with striking capacity retention of 81 % after 500 cycles at 0.5 A g(-1). In addition, a Cu-CAT NWs-based full cell assembled with LiNi0.8Co0.1Mn0.1O2 as the cathode displayed a large energy density of approximately 275 Wh kg(-1) as well as excellent cycling behavior. These results manifest the promising application of 1D conductive Cu-CAT NWs in advanced LIBs and even other potential versatile energy-related fields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available