Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 71, Pages 16214-16218Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903789
Keywords
bioinorganic chemistry; caged nucleosides; metal-mediated base pairs; nucleic acids; thymidine
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Funding
- Westfalische Wilhelms-Universitat Manster
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By applying caged thymidine residues, DNA duplexes were created in which Hg-II-mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal-mediated base pairs was achieved.
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