Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 10, Pages 2099-2119Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903442
Keywords
amidines; dinuclear complexes; dinucleating ligands; guanidines; mononuclear complexes
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Funding
- German Young Academy (Die Junge Akademie)
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG) [KR4782/2-1, KR4782/3-1]
- Friedrich Schiller University Jena
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Polytopic ligands have become ubiquitous in coordination chemistry because they grant access to a variety of mono- and polynuclear complexes of transition metals as well as rare-earth and main-group elements. Nitrogen-based ditopic ligands, in which two monoanionic N,N-binding sites are framed within one molecule, are of particular importance and are therefore the primary focus of this review. In detail, bis(amidine)s, bis(guanidine)s, bis(beta-diimine)s, bis(aminotroponimine)s, bis(pyrrolimine)s, and miscellaneous bis(N,N-chelating) ligands are reviewed. In addition to the general synthetic protocols, the application of these ligands is discussed along with their coordination chemistry, the multifarious binding modes, and the ability of these ligands to bridge two (or more) metal(loids).
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