Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 17, Pages 3688-3697Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904794
Keywords
alkoxides; lithium; magnesium; metal-halogen exchange; zinc
Categories
Funding
- DFG [SFB749]
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For the preparation of zinc organometallics bearing highly sensitive functional groups such as ketones, aldehydes or nitro groups, especially mild halogen-zinc exchange reagents have proven to be of great potential. In this Minireview, the latest research in the area of the halogen-zinc exchange reaction is reported, with a special focus lying on novel dialkylzinc reagents complexed with lithium alkoxides. Additionally, the preparation and application of organofluorine zinc reagents and transition-metal-catalyzed halogen-zinc exchange reactions are reviewed.
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