Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 22, Pages 4895-4916Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904495
Keywords
bimetallic catalysis; cross-coupling; Sonogashira reaction; stereodivergent synthesis; synergistic Pd; Cu catalysis
Categories
Funding
- Shanghai Sailing Program [19YF1421900]
- Shanghai Municipal Education Commission [201701070002E00030]
- Science and Technology Commission of Shanghai Municipality [19JC1430100]
- National Natural Science Foundation of China [21620102003, 21831005, 21901158, 21991112]
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Synergistic Pd/Cu catalysis has been utilized in the Sonogashira reaction since 1975. However, this strategy has not received much attention from the organic chemist community until recently. Synergistic Pd/Cu catalysis is becoming a proficient method for the development of catalytic reactions, including several new and efficient cross-coupling reactions. Additionally, several challenging asymmetric reactions, including stereodivergent synthesis, have been discovered by the combined use of a chiral metal catalyst and a second achiral metal catalyst or two chiral metal catalysts. This review provides an overview of this field, with the aims of highlighting both the development of synergistic Pd/Cu catalysis in organic synthesis and the reaction mechanisms involved in this research area.
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