Journal
CHEMISTRY OF MATERIALS
Volume 31, Issue 22, Pages 9472-9479Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.9b03439
Keywords
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]
- FAPESP [2016/02268-9, 2017/11019-5]
- FAPESP (the Sao Paulo Research Foundation) [2017/11986-5]
- Shell
- ANP (Brazil's National Oil, Natural Gas and Biofuels Agency)
- Center for Hybrid Organic Inorganic Semiconductors for Energy (CHOISE), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-AC36-08G028308]
- NSF
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [16/02268-9, 17/11986-5] Funding Source: FAPESP
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Ruddlesden-Popper organic lead halides (RPOLHs) are in the material science spotlight because of their remarkable optoelectronic properties, tailorable compositions, and improved ambient stability over their three-dimensional perovskite analogues. In this report, we introduce a new synthesis method for RPOLHs with general composition L-2[FAPbI(3)](n-1)PbI4 [L = butylammonium (BA) or benzylammonium (BZA), FA = formamidinium, and n = 1 and 2]. Our method yields polycrystalline materials useful for thin-film fabrication for optoelectronic applications. Furthermore, we report the growth dynamics of BA(2)[FAPbI(3)]PbI4 using in situ small-angle X-ray scattering, revealing that the slabs grow within the first seconds of the reaction and then self-assemble into bulk crystallites.
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