Journal
CHEMISTRY LETTERS
Volume 49, Issue 2, Pages 141-144Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190795
Keywords
Germanium; Germanethione; Germanone
Categories
Funding
- MEXT-Supported Program for the Strategic Research Foundation at Private Universities 2014-2018
- JSPS-CNRS Bilateral Open Partnership Joint Research Projects [I2017650]
- JSPS [18F18036]
- [JP15H03788]
- [18K05160]
- [JP19002008]
- [2408]
- [JP20109003]
- [JP15H00964]
- Grants-in-Aid for Scientific Research [18F18036] Funding Source: KAKEN
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A new diarylgermanethione, (Eind)(2)Ge=S, supported by the fused-ring bulky Eind groups (Eind = 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl) has been obtained as yellow-orange crystals by the direct reaction between the diarylgermylene, (Eind)(2)Ge:, and elemental sulfur in solution. The structure and bonding nature of the germanethione have been compared to those of its oxygen congener, germanone, (Eind)(2)Ge=O. We also report the X-ray structure analysis of the hydroxy(mercapto)germane, (Eind)(2)Ge(OH)(SH).
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