4.5 Article

Pr-doped Modified Fe-Mn/TiO2 Catalysts with a High Activity and SO2 Tolerance for NH3-SCR at Low-Temperature

Journal

CATALYSIS LETTERS
Volume 150, Issue 4, Pages 1041-1048

Publisher

SPRINGER
DOI: 10.1007/s10562-019-03019-8

Keywords

Fe-Mn; TiO2 catalyst; NH3-SCR; Low temperature; Pr modification; SO2 resistance

Funding

  1. Foundation of Hebei (in China) Education Department [ZD2015116]
  2. Foundation of Hebei Province of China [B2017209111]

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Pr-modified Fe-Mn/TiO2 (x Pr) catalysts with high activity and excellent SO2 resistance were prepared and used for the selective catalytic reduction of NO with NH3 (NH3-SCR) at low-temperatures. Pr can inhibit FeOx and MnOx crystallization and stabilize the high valence states of Fe and Mn, maintaining the catalyst's high activity and stability at low temperatures. Doping with Pr diminished the ammonium sulfate deposition and alleviated the sulfation, improving the catalysts' sulfur resistance. Graphic

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