Electrochemical pretreatment of yard waste to improve biogas production: Understanding the mechanism of delignification, and energy balance

In the present study, electrochemical pretreatment with a pair of graphite electrode was conducted to pretreat yard waste prior to anaerobic digestion. The Response Surface Methodology was employed to optimize the pretreatment conditions. To determine the mechanism of delignification physical and chemical properties of untreated and pretreated yard waste were investigated. In the subsequent anaerobic digestion of pretreated yard waste, the ultimate biogas production of 446 mL/g VS was achieved in comparison to the untreated yard waste of 287 mL/g VS on 35th day of anaerobic digestion. A net energy gain of 4.75 kJ/g VS (Output energy of 5.73 kJ/g VS - Input energy of 0.98 kJ/g VS) and net profit of 518 rupees (US$ 7.4) per 1 ton of yard waste indicates the applicability of electrochemical pretreatment for pilot scale.