Journal
APPLIED SPECTROSCOPY
Volume 74, Issue 12, Pages 1443-1451Publisher
SAGE PUBLICATIONS INC
DOI: 10.1177/0003702819885002
Keywords
Spectroscopy process; baseline correction; penalized least squares; constraint condition
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Baseline drift occurs in various measured spectra, and the existence of a baseline signal will influence qualitative and quantitative analyses. Therefore, it is necessary to perform baseline correction or background elimination before spectral analysis. In this paper, a multiple constrained asymmetric least squares method based on the penalized least squares principle is proposed for baseline correction. The method takes both baseline and peak characteristics into account. Based on the prior knowledge that the left and right boundaries of characteristic peaks should be symmetrical, additional constraints of penalized least squares are added, which ensure the symmetry of spectra. The experimental results of the proposed method on simulated spectra are compared with existing baseline correction methods to verify the accuracy and adaptability of the proposed method. The method is also successfully applied to the baseline correction of real spectra. The results show that it can be effective for estimating the baseline. In addition, this method can also be applied to the baseline correction of other similar spectral signals.
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