Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 42, Pages 14891-14895Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906324
Keywords
actinides; neptunium; organometallics; oxidation; structure elucidation
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Funding
- Department of Energy, Early Career Award Program [DESC-0014174]
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division (CSGB), Heavy Element Chemistry Program
- Lawrence Berkeley National Laboratory [DE-AC02-05CH11231]
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To extend organoactinide chemistry beyond uranium, reported here is the first structurally characterized transuranic hydrocarbyl complex, Np[eta(4)-Me2NC(H)C6H5](3) (1), from reaction of NpCl4(DME)(2) with four equivalents of K[Me2NC(H)C6H5]. Unlike the U-III species, the neptunium analogue can be used to access other Np-III complexes. The reaction of 1 with three equivalents of HE2C(2,6-Mes(2)-C6H3) (E=O, S) yields [(2,6-Mes(2)-C6H3)CE2](3)Np(THF)(2), maintaining the trivalent oxidation state.
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