Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 43, Pages 15318-15323Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201908850
Keywords
cyclononatetraenyl; cyclooctatetraene; palladium clusters; sandwich complexes
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Funding
- JSPS, Japan [18H01993, 18H04645, 17KT0102, 19H04565]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [19H04565, 17KT0102, 18H01993, 18H04645] Funding Source: KAKEN
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The ligand-unsupported accommodation of extra metal moieties in a sandwich complex is reported. Although it has been considered that the metal-capacity of a metal sheet sandwich complex is strictly limited by the size of cyclic unsaturated hydrocarbon ligands, the M-M edge bonds in a metal sheet sandwich complex provide a ligand-unsupported docking site for extra metal moieties, allowing expansion of metal-capacity in sandwich complexes. The metal sheet sandwich complex [Pd-4(mu(4)-C8H8)(mu(4)-C9H9)](+), in which the ligand-based metal capacity is full in terms of the usage of all C=C moieties of the smaller carbocyclic ligand C8H8 in coordination, can accommodate extra M-0{P(OPh)(3)}(2) (M=Pd, Pt) moieties without coordinative assistance by either the C9H9 or the C8H8 ligand.
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