Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 8, Pages 3166-3171Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201912343
Keywords
blue LEDs; carbon dots; cytotoxicity; free radical photopolymerization; photo-ATRP
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Funding
- National Natural Science Foundation of China [31890774, 31800494]
- Young Elite Scientists Sponsorship Program (CAST) [2018QNRC001]
- state of North Rhine-Westphalia [005-1703-0006]
- European Union
- MWIDE of NRW
- Ministerie van Economische Zaken en Klimaat
- province of Limburg
- province of Gelderland
- province of Noord-Brabant
- province of Overijssel
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Carbon dots (CDs) have been used for the first time as a sensitizer to initiate and activate free radical and controlled radical polymerization, respectively, based on an ATRP protocol with blue LEDs. Consideration of diverse heteroatom-doped CDs indicated that N-doped CDs could serve as an effective photocatalyst and photosensitizer in combination with LEDs emitting either at 405 nm or 470 nm. Free radical polymerization was initiated by combining the CDs with an iodonium or sulfonium salt in tri(propylene glycol) diacrylate. Polymerization of methyl methacrylate (MMA) by photo-induced ATRP was achieved with CDs and ethyl alpha-bromophenylacetate using Cu-II as catalyst in the ppm range. The polymers obtained showed temporal control, narrower dispersity less than or similar to 1.5, and chain-end fidelity. The first-order kinetics and ON/OFF experiments additionally gave evidence of the constant concentration of polymer radicals. No remarkable cytotoxic activity was observed for the CDs, underlining their biocompatibility.
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