4.8 Article

Hierarchical Nanostructured NiS/MoS2/C Composite Hollow Spheres for High Performance Sodium-Ion Storage Performance

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 44, Pages 41222-41228

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b11078

Keywords

composite hollow spheres; sodium ion batteries; nickel sulfides; molybdenum sulfides; nanosheets

Funding

  1. National Key Research and Development Program of China [2017YFA0204600]
  2. National Natural Science Foundation of China [51721002, 51673045]

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Development of high performance electrode materials for sodium-ion batteries has been given a lot of attention in recent years but challenges remain. Herein, we have successfully synthesized the first NiS/MoS2/C composite hollow spheres (NMSCHSs) via a facile hard template method combined with calcined sulfidation process. Owing to its unique hierarchical nanostructure with NiS nanoparticles embedded in shell wrapped with MoS2 nanosheets, the NMSCHS-based anode electrodes exhibit superior rate capability and cycling stability, with a specific discharge capacity of 516 mAh g(-1) and 98.5% retention after 60 cycles at a current density of 0.1 A g(-1) and a discharge capacity of 398 mAh g(-1) even at 5 A g(-1).

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