What Causes Carbonates to Form Shrubby Morphologies? An Anthropocene Limestone Case Study

The South Atlantic Aptian Pre-Salt shrubby carbonate successions offshore Brazil and Angola are of major interest due to their potential hydrocarbon accumulations. Although the general sedimentology of these deposits is widely recognized to be within saline, alkaline lakes in rift volcanic settings, the specific genesis of shrubby carbonate morphologies remains unclear. This study reports the first petrographically comparable shrubby carbonates amongst other carbonate microfacies from an Anthropocene limestone formed under hyperalkaline (pH 9-12) and hypersaline (conductivity 425-3200 mu S) conditions at ambient temperature (12.5-13 degrees C) (Consett, United Kingdom). This discovery allows us to capitalize on exceptional long-term hydrochemical monitoring efforts from the site, demonstrating that shrubby carbonates occur uniquely within the waters richest in calcium (similar to 240 mg/L) and with highest pH (similar to 12) and consequently with very high levels of supersaturation. However, the physical distribution of shrubs is more comparable with estimated local kinetic precipitation rate than it is to thermodynamic saturation, indicating that the fundamental control on shrub formation arises from crystal surface processes. The shrubby carbonate we report grows in the presence of significant diatomaceous and cyanobacterial biofilms, despite the highly alkaline conditions. These biofilms are lost from the deposited material early due to the high solubility of organic and silica within hyperalkaline settings, and this loss contributes to very high intercrystalline porosity. Despite the presence of these microbes, few if any of the fabrics we report would be considered as boundstones despite it being clear that most fabrics are being deposited in the presence of abundant extra-cellular polymeric substances. We are aware of no previous petrographic work on anthropogenic carbonates of this type, and recommend further investigation to capitalize on what can be learned from these accidental laboratories.