Journal
SCIENCE BULLETIN
Volume 64, Issue 24, Pages 1896-1901Publisher
ELSEVIER
DOI: 10.1016/j.scib.2019.08.014
Keywords
Bisphosphonium salt; Hydroalkoxylation; Photoredox catalysis
Categories
Funding
- National Natural Science Foundation of China [21702029, 21772121]
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A photocatalytic, intramolecular hydroalkoxylation of alkenes has been achieved by utilizing simple and readily available biphosphonium salts as an effective organic photocatalyst. The unique photocatalytic properties of biphosphonium salt enables facile oxidations of substituted alkenes to facilitate the streamline and regioselective synthesis of a series of saturated cyclic ethers from simple alkenes under mild conditions. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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