Mineral Composition, Pore Structure, and Mechanical Characteristics of Pyroxene Granite Exposed to Heat Treatments

In deep geoengineering, including geothermal development, deep mining, and nuclear waste geological disposal, high temperature significantly affects the mineral properties of rocks, thereby changing their porous and mechanical characteristics. This paper experimentally studied the changes in mineral composition, pore structure, and mechanical characteristics of pyroxene granite heated to high temperature (from 25 degrees C to 1200 degrees C). The results concluded that (1) the high-temperature effect can be roughly identified as three stages: 25-500 degrees C, 500-800 degrees C, 800-1200 degrees C. (2) Below 500 degrees C, the maximum diffracted intensities of the essential minerals are comparatively stable and the porous and mechanical characteristics of granite samples change slightly, mainly due to mineral dehydration and uncoordinated thermal expansion; additionally, the failure mechanism of granite is brittle. (3) In 500-800 degrees C, the diffraction angles of the minerals become wider, pyroxene and quartz undergo phase transitions, and the difference in thermal expansion among minerals reaches a peak; the rock porosity increases rapidly by 1.95 times, and the newly created pores caused by high heat treatment are mainly medium ones with radii between 1 mu m and 10 mu m; the P-wave velocity and the elastic modulus decrease by 62.5% and 34.6%, respectively, and the peak strain increases greatly by 105.7%, indicating the failure mode changes from brittle to quasi-brittle. (4) In 800-1200 degrees C, illite and quartz react chemically to produce mullite and the crystal state of the minerals deteriorate dramatically; the porous and mechanical parameters of granite samples all change significantly and the P-wave, the uniaxial compressive strength (UCS), and the elastic modulus decrease by 81.30%, 81.20%, and 92.52%, while the rock porosity and the shear-slip strain increase by 4.10 times and 11.37 times, respectively; the failure mechanism of granite samples transforms from quasi-brittle to plastic, which also was confirmed with scanning electron microscopy (SEM).