Journal
CHEMELECTROCHEM
Volume 6, Issue 21, Pages 5407-5412Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201901420
Keywords
3D graphene foam; self-supporting electrodes; NiFe phosphide; high stability; bifunctional electrocatalysts
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Funding
- National Natural Science Foundation of China [51502092]
- Fundamental Research Funds for the Central Universities [222201718002]
- Thousand Talents Program Young Project in China
- Program for Eastern Scholar at Shanghai Institutions of Higher Learning [TP2015028]
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The development of stable non-noble metal-based electrocatalysts with high performance for overall water splitting is critical in the field of renewable energy. Herein, we combined nickel iron phosphide (NiFe-P) nanosheets with three-dimensional porous graphene foam (3DGF) as a substrate to design a bifunctional electrocatalyst NiFe-P@3DGF with excellent catalytic activity towards oxygen and hydrogen evolution reactions (OER and HER, respectively) under alkaline conditions. At a current density of 10 mA cm(-2), the overpotentials for the OER and HER are less than 189 and 131 mV, respectively, and the stabilities exceed 50 h. Furthermore, this bifunctional catalyst also exhibits excellent water-splitting capability with a cell voltage of 1.57 V at 10 mA cm(-2). The special structure of the 3DGF substrate with its large surface area, high conductivity, and robust skeleton, as well as the unique core-shell structure of NiFe (oxy)hydroxides/phosphide formed throughout the reaction promote the high activity of the electrocatalyst. Therefore, this work provides a new perspective to exploit the efficient bifunctional electrocatalyst using porous 3DGF as the substrate.
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