Journal
NANO-MICRO LETTERS
Volume 11, Issue 1, Pages -Publisher
SHANGHAI JIAO TONG UNIV PRESS
DOI: 10.1007/s40820-019-0297-6
Keywords
SnS2; Graphene fiber fabric; Binder-free electrode; Practical capacity; Sodium-ion batteries
Funding
- National Natural Science Foundation of China [21503025, 21503178, 21603019]
- Fundamental Research Funds for the Central Universities [0903005203377, 106112016CDJZR325520]
- Key Program for International Science and Technology Cooperation Projects of Ministry of Science and Technology of China [2016YFE0125900]
- Venture and Innovation Support Program for Chongqing Overseas Returnees [cx2017060, cx2017115]
- Chongqing Research Program of Basic Research and Frontier Technology [cstc2016jcyjA1059]
- Hundred Talents Program of Chongqing University
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Generally, the practical capacity of an electrode should include the weight of non-active components such as current collector, polymer binder, and conductive additives, which were as high as 70 wt% in current reported works, seriously limiting the practical capacity. This work pioneered the usage of ultralight reduced graphene fiber (rGF) fabrics as conductive scaffolds, aiming to reduce the weight of non-active components and enhance the practical capacity. Ultrathin SnS2 nanosheets/rGF hybrids were prepared and used as binder-free electrodes of sodium-ion batteries (SIBs). The interfused graphene fibers endow the electrode a porous, continuous, and conductive network. The in situ phase transformation from SnO2 to SnS2 could preserve the strong interfacial interactions between SnS2 and graphene. Benefitting from these, the designed binder-free electrode delivers a high specific capacity of 500 mAh g(-1) after 500 cycles at a current rate of 0.5 A g(-1) with almost 100% Coulombic efficiency. Furthermore, the weight percentage of SnS2 in the whole electrode could reach up to 67.2 wt%, much higher than that of common electrode configurations using Cu foil, Al foil, or carbon cloth, significantly highlighting the ultralight characters and advantages of the rGF fabrics for using as binder-free electrodes of SIBs.
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