Journal
WATER RESEARCH
Volume 161, Issue -, Pages 89-97Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2019.05.098
Keywords
Urea; Vacuum ultraviolet; Swimming pool water; Photolysis; 185 nm
Funding
- Shenzhen Science and Technology Innovation Commission [JCYJ20180306171820685]
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To discover an applicable technology for urea abatement from swimming pool water (SPW), this study compared the performances of seven ultraviolet (UV)-based technologies on urea removal, including UV alone, UV coupled with hydrogen peroxide (UV/H2O2), sulfite (UV/Na2SO3), potassium persulfate (UV/K2S2O8), a combination of UV and vacuum UV (UV/VUV), and UV/VUV in tandem with either H2O2 (VUV/H2O2) or potassium persulfate (VUV/K2S2O8). Among them, UV and UV/Na2SO3 showed little removal ability, and UV/H2O2 removed only 12.8% of urea within 3-h experiments, while UV/VUV degraded 71.7% of urea without introducing substantial total dissolved solids (TDS). Therefore, UV/VUV was considered as a promising technology for further exploration. In comparison, although UV/K2S2O8 exhibited higher urea removal than UV/VUV, it caused dramatic increases of TDS, which made the regulatory threshold for the TDS increment difficult to maintain. Within UV/VUV studies, some common components in SPW (e.g., cyanuric acid, humic acid, nitrate, and bicarbonate) inhibited the removal process, whereas chloride and sulfate facilitated it, while free chlorine at doses <= 3 mg-Cl-2/L and pH levels from 6.8 to 8.0 imposed little impact on urea degradation. Overall, UV/VUV degraded 40.0% and 22.2% of urea from tap water and SPW, respectively; both were lower than the efficiency observed in ultrapure water. As for reaction byproducts, urea phototransformation via UV/VUV yielded nitrate and ammonia as the key products with the mass balance of nitrogen element being met. However, the contents of organic carbon decreased at a rate slightly lower than urea degradation, suggesting that urea was mostly mineralized and slightly converted to unknown organic compounds. The results hence demonstrate that UV/VUV is an effective alternative for urea removal from SPW. (C) 2019 Elsevier Ltd. All rights reserved.
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