Photoelectrocatalytic degradation of organics and formation of disinfection byproducts in reverse osmosis concentrate

The high content of organics in municipal reverse osmosis concentrate (ROC) requires proper treatment. Here, this study applied the photoelectrocatalysis (PEC) to reduce the concentration of organics in ROC. Meanwhile, the formation of disinfection byproducts (DBPs) was investigated. Participation of primary oxidants in organics removal and DBPs formation was revealed at different anodic potentials and pHs. The results showed that PEC process effectively oxidized the organics in ROC, achieving the highest mineralization rate of 63%. Increasing anodic potential from 0 to 1.0 V enhanced the oxidations of bulk organics (i.e., dissolved organic carbons (DOC), UV254, fluorescence, large molecular weight compounds) and trace-level pharmaceuticals. Raising anodic potential to higher than 1.0 V slightly benefited the oxidations of bulk organics, owing to the relatively stable formation of hydroxyl radicals (OH.) and radical reactive chlorine species (r-RCS). The continuously rising concentration of free chlorine (FC) accelerated the decompositions of pharmaceuticals at >= 1.0 V. However, the generated FC raised the concentration of DBPs up to 10.36 mu mol/L at 3.0 V. Lowering initial pH from 7-9 to 4-6 improved the mineralization rates by around 20% due to the higher formation of OH. at pH 4-6. Further decreasing initial pH from 6 to 4 enhanced the breakdown of large molecular weight compounds as well as the decomposition of pharmaceuticals. This came from the strengthened formation of FC and r-RCS at lower pHs. The intense participation of FC and r-RCS resulted in a higher total DBP concentration at pH 4-6 than that at pH 7-9. However, the individual species of DBPs changed differently toward the pH shift. The results of this study show that PEC could be an alternative for organics oxidation in ROC with proper control of DBPs formation. (C) 2019 Elsevier Ltd. All rights reserved.