4.7 Article

Recovery and regeneration of LiCoO2-based spent lithium-ion batteries by a carbothermic reduction vacuum pyrolysis approach: Controlling the recovery of CoO or Co

Journal

WASTE MANAGEMENT
Volume 97, Issue -, Pages 140-148

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2019.08.004

Keywords

Spent lithium-ion batteries; LiCoO2; Recovery; Regeneration; Vacuum pyrolysis

Funding

  1. Fundamental Research Funds for the Central Universities [N172505002]
  2. NSFC [51704060]
  3. National Thousand Youth Talent Program of China
  4. 111 Project [B16009]

Ask authors/readers for more resources

An environmentally benign vacuum pyrolysis (VP) approach is employed to recover Li and Co from spent LiCoO2-based lithium-ion batteries (LIBs). First, the electroactive materials were separated from the current collector by the VP method from 623 to 823 K with an attempt to choose an appropriate temperature. Then, the as-received cathode materials were mixed with different amounts of graphite from the anode to selectively convert LiCoO2 to Co or CoO and Li2CO3 by carbothermic reduction under vacuum and at 873 to 1273 K. After carbothermic reduction, the pyrolyzed powder was leached in water to separate Li2CO3 from Co/CoO. By alternating the C/LiCoO2 mass ratio and the pyrolysis temperature, a recovery rate reaches over 93% for Li and 99% for Co. Finally, the recovered CoO and Li2CO3 were used to regenerated LiCoO2 that delivered a specific capacity of 145 mAh g(-1) at 1C and retaining 93% of the initial capacity after 100 cycles. Overall, a multi-vacuum-pyrolysis approach offers a closed-loop route for the management of spent LIBs without using any hazardous chemicals. (C) 2019 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available