Journal
TETRAHEDRON LETTERS
Volume 60, Issue 38, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.151046
Keywords
EDA complex; Visible-light irradiation; C-H perfluoroalkylation; Quinolinone
Categories
Funding
- National Natural Science Foundation of China [21502019, 21402027]
- Science Foundation of the Fujian Province, China [2019J01203]
- Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment [SKLPEE-KF201816]
- Foundation of Science and Technology on Sanming Institute of Fluorochemical Industry [FCIT2017028R]
- Fuzhou University
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An efficient method for visible-light-induced perfluoroalkylaion of quinolin-4-ol has been reported. In the presence of t-BuONa and perfluoroalkyl iodide, quinolin-4-ol underwent C-H perfluoroalkylation under the irradiation of green light. Mechanistic studies demonstrated that visible-light promoted intermolecular charge transfer within the transient electron donor-acceptor complex in the absence of any photocatalysts. (C) 2019 Elsevier Ltd. All rights reserved.
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