Journal
SYNLETT
Volume 30, Issue 15, Pages 1830-1834Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1690163
Keywords
hydroxysulfenylation; hydroxy sulfides; iodine catalysis; green chemistry
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Funding
- National Natural Science Foundation of China [21808085]
- China Postdoctoral Science Foundation [2018M630519]
- Natural Science Foundation of Jiangsu Province, China [BK20160164]
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An environmentally friendly and efficient strategy has been developed for preparing beta-hydroxy sulfides by a molecular-iodine-catalyzed radical reaction. This reaction involves hydroxysulfenylation of alkenes with disulfides in aqueous solution. Air is used as the oxidant without any additives. Control experiments indicated that the oxygen atom of products might come from O-2. Both aryl alkenes and aliphatic alkenes were well tolerated in this transformation and afforded the corresponding products in moderate to high yields.
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