Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 12, Issue -, Pages 2577-2587Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.12.253
Keywords
aza-Wittig reactions; catalysis; phosphines; phosphine oxides; reduction; silanes; Wittig reactions
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Funding
- University of Hong Kong
- Research Grants Council of the Hong Kong S. A. R., P. R. of China [GRF 17305915]
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This review surveys the literature regarding the development of catalytic versions of the Wittig and aza-Wittig reactions. The first section summarizes how arsenic and tellurium-based catalytic Wittig-type reaction systems were developed first due to the relatively easy reduction of the oxides involved. This is followed by a presentation of the current state of the art regarding phosphine-catalyzed Wittig reactions. The second section covers the field of related catalytic aza-Wittig reactions that are catalyzed by both phosphine oxides and phosphines.
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