Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 89, Issue 8, Pages 1649-1652Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363219080164
Keywords
Schiff bases; malonic acid hydrazide; manganese(II) complexes; iron(III) complexes
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New manganese(II) and iron(III) complexes with hydrazones derived from malonic acid dihydrazide and 3,5-di-tert-butylsalicylaldehyde have been synthesized. The structure of the complexes has been studied by IR and electronic spectroscopy and X-ray analysis. Malonic acid bis[(2-hydroxy-3,5-di-tert-butylbenzylidene)-hydrazide] has been shown to form dinuclear complexes with manganese and iron ions, in which ferromagnetic interaction between the metal ions is observed.
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