Journal
ORGANIC PROCESS RESEARCH & DEVELOPMENT
Volume 23, Issue 8, Pages 1758-1761Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.9b00280
Keywords
beta(3)-amino acids; asymmetric allylation; iridium
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Funding
- National Natural Science Foundation [21772125, 21602145]
- Sichuan University
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A method to prepare chiral beta(3)-amino esters from methyl 3-aminopropanoate was described. This method capitalized on a sequence involving an Ir-catalyzed asymmetric allylation of 2-azaallyl anions and a 2-aza-Cope rearrangement. beta(3)-Amino esters containing a versatile alkene group were prepared.
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