Journal
ORGANIC LETTERS
Volume 21, Issue 18, Pages 7445-7449Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02753
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Funding
- National Natural Science Foundation of China [21401104]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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A new donor-acceptor Stenhouse adduct based on a N,N,N'-trimethylethylenediamine donor has been reported. An unprecedented isomer has been isolated, and rich conversions between three isomers have been achieved upon visible-light irradiation or base/acid stimuli. The drastic color change associated with structural conversion has been utilized to selectively sense volatile primary amines as well as high-charged hard Lewis acids (Sc3+, Ti4+, Cr3+, and Al3+).
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