4.8 Article

HBF4- and AgBF4-Catalyzed ortho-Alkylation of Diarylamines and Phenols

Journal

ORGANIC LETTERS
Volume 21, Issue 17, Pages 6830-6834

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02470

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Funding

  1. DFG [SFB/TRR 88, PA 2395/2-1]
  2. ERC [716136]

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A silver-tetrafluoroborate- or HBF4-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.

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