Journal
ORGANIC LETTERS
Volume 21, Issue 17, Pages 7104-7108Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02675
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Funding
- Natural Science Foundation of China [21602168]
- Fundamental Research Funds of the Central Universities [xjj2017027]
- Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology [201805056ZD7CG40]
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An iron-catalyzed decarboxylative olefination of unstrained carbon-carbon bonds via alkoxyl radical induced C-C bond cleavage is presented. This protocol features mild conditions (room temperature, redox-neutral), good substrate scope and functional group compatibility, as well as excellent stereoselectivity, thus providing a facile access to the distal alkenyl ketones.
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