Journal
ORGANIC LETTERS
Volume 21, Issue 19, Pages 8138-8143Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03243
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Funding
- NISER
- Department of Atomic Energy (DAE)
- Council for Scientific and Industrial Research (CSIR), New Delhi [02(0256)/16/EMR II]
- Science and Engineering Research Board (SERB), New Delhi [EMRII/2017/001475]
- DAE
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Herein, we disclosed the first report on the selective C(4)-H functionalization of 3-acetylindole derivatives using first-row transition metal cobalt where an acetyl group is acting as a weakly coordinating directing group. Selective C(4)-H functionalization has been achieved using diverse Michael acceptors (acrylate and maleimide) simply by switching the additive from copper acetate to silver carbonate. Further the formation of acobaltacycle intermediate was also detected through HRMS for mechanistic insight.
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