Journal
ORGANIC LETTERS
Volume 21, Issue 19, Pages 8071-8074Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03070
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Funding
- JSPS KAKENHI [JP17H06450, JP26220803, JP18H01975]
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A novel chiral motif based on a phenylcyclopropane scaffold has been designed, and a facile synthetic route to the key intermediate for the synthesis of phenylcyclopropane-based chiral secondary amines has been developed. Newly synthesized chiral amines function as effective catalysts for several asymmetric reactions through enamine intermediates.
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