Journal
ORGANIC LETTERS
Volume 21, Issue 19, Pages 7713-7716Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02449
Keywords
-
Categories
Funding
- Centre National de la Recherche Scientifique (CNRS), the Universite de Rennes 1
- Universite Toulouse III
- Institut Universitaire de France (IUF)
- Embassy of Yemen in Paris
- program Pause
Ask authors/readers for more resources
Re-2(CO)(10) efficiently catalyzes the direct reduction of various carboxylic acids under mild conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily converted to the corresponding disilylacetals with low catalyst loading (0.5 mol %) in the presence of Et3SiH (2.2 equiv), aromatic analogues required more drastic conditions (Re-2(CO)(10) 5 mol %, Ph2MeSiH 4.0 equiv) to afford the corresponding aldehydes after acid treatment.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available