4.7 Article

Synthesis of porous MoS2/CdSe/TiO2 photoanodes for photoelectrochemical water splitting

Journal

MICROPOROUS AND MESOPOROUS MATERIALS
Volume 284, Issue -, Pages 403-409

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2019.04.055

Keywords

CdSe; MoS2; TiO2; Photocatalyst; Photoelectrochemical; Water splitting

Funding

  1. National Natural Science Foundation of China [21273010]
  2. Program for Natural Science of Henan Province [162300410004]
  3. Key Scientific Research Projects of Henan Universities [19A150014]
  4. Anyang Normal University College Student Innovation Fund Project [ASCX/2018-Z044]
  5. Fundamental Technology Research Program through the National Research Foundation of Korea
  6. Korean government [2014M3A7B4052201]

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Herein, MoS2/CdSe/TiO2 ternary composites have been successfully synthesized by a simple approach. The SEM and TEM results demonstrate that MoS2/CdSe/TiO2 ternary composites have a porous structure, which can provide more active sites and mass charge transport pathways in a catalytic system. The optical measurement demonstrates that the MoS2 and CdSe coexisted in the porous TiO2 structure, which results in a wider visible light absorption than that of pure TiO2. Most importantly, the photoelectrochemical measurement results demonstrate that such ternary composite catalysts exhibit a higher photocurrent performance than that of a binary composite and pure TiO2, owing to the strong synergistic effects among MoS2, CdSe, and TiO2. These superior results show that MoS2/CdSe/TiO2 ternary composites is a promising choice for photoelectrochemical water splitting.

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