Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 140, Issue 1, Pages 95-107Publisher
SPRINGER
DOI: 10.1007/s10973-019-08846-w
Keywords
Mechanical activation; DTA; Raman spectroscopy; Sintering kinetics; Spinel
Funding
- Serbian Ministry of Education, Science and Technological Development of the Republic of Serbia [OI 172057]
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Solid-state mechanical activation of MgO and alpha-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 degrees C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)(2) shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 degrees C for non-activated samples, and 1400 degrees C for activated samples.
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